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From Digital Photography Review
Photoshop CS6 Beta: New Features for Photographers
From Tim Grey (download video)
From Laura Show (video)
Laura also has a separate post summarizing additional Photoshop CS6 Beta features here.
If you use a Mac for running Photoshop, you should be aware that the new version will NOT run on 32-bit Mac systems. Your computer must be a 64-bit Intel processor machine for Photoshop CS6. More details and a link to download a free copy of Photoshop CS6 Beta are available at the Adobe Labs web site.